李智课题组介绍
课题组长 |
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研究介绍 |
催化剂和催化反应是当代化学工业的重要组成部分,催化领域的研究不仅具有基础理论与学术意义、重大的工业应用价值,更可能成为解决当前人类面临的可持续发展问题的关键。在碳中和、可再生资源转化、绿色化工过程和绿色制药化学等新问题的研究过程中,催化剂和催化反应都将起到至关重要的作用。面向这些方向,我们将着力于(1)研究新型路易斯酸催化剂的设计与合成,以及它们在(2)可再生资源转化、塑料降解、(3)有机合成与制药化学中的应用,促进化学工业向绿色可持续方向发展。 |
发表论文 |
Independent Publications:
PhD & Postdoc publications: 1. Lohr, T. L.; Li, Z.; Marks, T. J.* Thermodynamic Strategies for C–O Bond Formation and Cleavage via Tandem Catalysis; Acc. Chem. Res., 2016, 49 (5), pp 824–834. 2. Lohr, T. L.; Li, Z.; Assary, R. S.; Curtiss, L. A.; Marks, T. J.* Mono- and tri-ester hydrogenolysis using tandem catalysis. Scope and mechanism; Energy Environ. Sci., 2016, 9 (2), pp 550–564. 3. Lohr, T. L.; Li, Z.; Marks, T. J.* Selective Ether/Ester C–O Cleavage of an Acetylated Lignin Model via Tandem Catalysis; ACS Catal., 2015, 5 (11), pp 7004–7007. 4. Lohr, T. L.†; Li, Z.†; Assary, R. S.; Curtiss, L. A.; Marks, T. J.* Thermodynamically Leveraged Tandem Catalysis for Ester RC(O)O–R′ Bond Hydrogenolysis. Scope and Mechanism; ACS Catal.,2015, 5 (6), pp 3675–3679. (Equal contribution) 5. Li, Z.; Assary, R. S.; Atesin, A. C.; Curtiss, L. A.; Marks, T. J.* Rapid Ether and Alcohol C-O Bond Hydrogenolysis Catalyzed by Tandem High-valent Metal Triflate + Supported Pd Catalysts; J. Am. Chem. Soc., 2014, 136, 104-107. 6. Assary, R. S.*; Atesin, A. C.; Li, Z.; Curtiss, L. A.*; Marks, T. J.* Reaction Pathways and Energetics of Etheric C–O Bond Cleavage Catalyzed by Lanthanide Triflates; ACS Catal., 2013, 3, 1908–1914. 7. Olivares-Romero, J. L.; Li, Z.; Yamamoto, H.* Catalytic Enantioselective Epoxidation of Tertiary Allylic and Homoallylic alcohols; J. Am. Chem. Soc., 2013, 135, 3411-3413. 8. Li, Z.; Yamamoto, H.* Hydroxamic Acids in Asymmetric Synthesis; Acc. Chem. Res.,2013,46, 506-518. 9. Olivares-Romero, J. L.; Li, Z.; Yamamoto, H.*; Hf(IV)-Catalyzed Enantioselective Epoxidation of N-Alkenyl Sulfonamides and N-Tosyl Imines; J. Am. Chem. Soc., 2012, 134, 5440-5443. (Top 20 Most Read Articles of March 2012) 10. Li, Z.; Yamamoto, H.*; Zirconium(IV)- and Hafnium(IV)-Catalyzed Highly Enantioselective Epoxidation of Homoallylic and Bishomoallylic Alcohols; J. Am. Chem. Soc. 2010, 132, 7878-7880. 11. Li, Z.; Zhang, W.; Yamamoto, H.*; Vanadium-Catalyzed Enantioselective Desymmetrization of meso-Secondary Allylic Alcohols and Homoallylic Alcohols; Angew. Chem. Int. Ed., 2008, 47, 7520-7522; Angew. Chem., 2008,120, 7630-7632. |
本组成员 |
Alain You Li, PhD
博士后 Ph.D. of McGill University Postdoc in Imperial College London (Marie-Curie Fellow)
邮箱:liay@@shanghaitech.edu.cn
姚嘉麟
18级研究生 中央民族大学学士
邮箱:yaojl@@shanghaitech.edu.cn
谷欢潮
21级研究生 上海科技大学学士
邮箱:guhch@@shanghaitech.edu.cn
张佳怡
21级研究生 南开大学学士
邮箱:zhangjy5@@shanghaitech.edu.cn
万远鼎
22级研究生 南昌大学学士
邮箱:wanyd2022@@shanghaitech.edu.cn
刘晨旭
22级研究生 大连理工大学学士
邮箱:liuchx2022@@shanghaitech.edu.cn
欧阳坤辰
20级本科生
邮箱:ouyangkch@@shanghaitech.edu.cn
葛逸飞
20级本科生
邮箱:geyf@@shanghaitech.edu.cn
姚羽泽
21级本科生
邮箱:yaoyz@@shanghaitech.edu.cn
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