李智

时间:2018-03-01浏览:20121设置

李智课题组介绍


课题组长
李智,副教授、研究员
通讯地址:2号楼506B
电子邮件:lizhi@@shanghaitech.edu.cn 
ORCID:https://orcid.org/0000-0003-2770-6364

学术经历:
2002-2006年就读于中国科学技术大学化学系,获学士学位(导师:尤田耙教授)
2006-2011年就读于美国芝加哥大学化学系,获博士学位(导师:Hisashi Yamamoto)
2010-2011 法国波尔多第一大学欧洲化学生物研究所(IECB)访问学生
2011-2014 美国西北大学化学系博士后(导师:Tobin J. Marks)
2015年3月加入金沙8888js官方担任助理教授。
2021年11月担任副教授。

所获荣誉:
中国科学院教育教学成果二等奖,2020
Thieme Chemistry Journal Award, 2018
Reaxys PhD Prize Finalists, Elsevier, 2012
Chateaubriand Scientific Fellowship, the Embassy of France in the US, 2010

研究介绍

  

催化剂和催化反应是当代化学工业的重要组成部分,催化领域的研究不仅具有基础理论与学术意义、重大的工业应用价值,更可能成为解决当前人类面临的可持续发展问题的关键。在碳中和、可再生资源转化、绿色化工过程和绿色制药化学等新问题的研究过程中,催化剂和催化反应都将起到至关重要的作用。面向这些方向,我们将着力于(1)研究新型路易斯酸催化剂的设计与合成,以及它们在(2)可再生资源转化、塑料降解、(3)有机合成与制药化学中的应用,促进化学工业向绿色可持续方向发展。


本课题组长期诚聘博士后研究员、硕博连读研究生,待遇优厚、课题前沿、工作环境优越,欢迎有志于在有机化学、催化化学等领域开展最先进研究的学生学者加入!有意者请直接与李智邮件联系。



发表论文

Independent Publications:

  1. Yao, J.-L.; Zhang, Z.; Li, Z.*; Scalable Transition-Metal-Free Synthesis of Aryl Amines from Aryl Chlorides through X@RONa-Catalyzed Benzyne Formation, J. Am. Chem. Soc. 2024, 146, 8839-8846.




  2. Luo, Y.-J.; Sun, J.-Y.; Li, Z.*; Rapid chemical recycling of waste polyester plastics catalyzed by recyclable catalyst, Green. Chem. Eng. 2024, 5, 257-265.

      




  3. Wang, T.; Shi, S.; Shi, Y.; Jiang, P.; Hu, G.; Ye, Q.; Shi, Z.; Yu, K.; Wang, C.; Fan, G.; Zhao, S.; Ma, H.; Chang, A. C. Y.; Li, Z.; Bian Q.*; Lin, C.-P.*; Chemical-induced phase transition and global conformational reorganization of chromatin, Nat. Commun. 2023, 14, 5556.

  4. Shi, Z.; Bian, Q.*; Li, Z.*; Access to N-Alkylazaheterocyclic Salts by Activation of Alkoxy C–O Bonds in Polyol Esters, J. Org. Chem. 2023, 88, 9769–9782.




  5. Ding, N.; Li, Z.*; Acid-catalyzed [4+1] dearomatization spiroannulation of hydroquinones and naphthols, Synlett; 2023, 34, 2417-2422. (Special issue dedicated to Prof. H. Yamamoto)



  6. Liu, D.-H.; He, H.-L.; Wang, J.-J.; Zhou, S.-Y.; Zeng, T.; Gao, X.-Y.; Xiao, Y.; Yi, X.; Zheng, A.; Zhang, Y.-B.; Li, Z.*; Acidic metal–organic framework empowered precise hydrodeoxygenation of bio-based furan compounds and cyclic ethers for sustainable fuels, Green. Chem. 2021, 23, 9974-9981.



  7. Xie, W.-B.; Li, Z.*; Bis(μ-oxo)–Dititanium(IV)–Chiral Binaphthyldisulfonate Complexes for Highly Enantioselective Intramolecular Hydroalkoxylation of Nonactivated Alkenes, ACS Catal., 2021, 11, 6270-6275.


  8. Liu, X.; Liu, B.; Shi, Z.; Tan, C.; Fan, R.; Li, Z.; Tan, J.*; Hf(OTf)4-Catalyzed 1,6-Conjugate Addition of 2-Alkyl-azaarenes to para-Quinone Methides, J. Org. Chem. 2021, 86, 3615-3624.

  9. Liu, D.-H.; He, H.-L.; Zhang, Y.-B.; Li, Z.*; Oxidative Aromatization of Biobased Chemicals to Benzene Derivatives through Tandem Catalysis, ACS Sustainable Chem. Eng. 2020, 8, 14322–14329.



  10. Ding, N.; Li, Z.*; When Anthracene and Quinone Avoid Cycloaddition: Acid-Catalyzed Redox Neutral Functionalization of Anthracene to Aryl Ethers, Org. Lett. 2020, 22, 4276-4282. (CBG: https://www.chembeango.com/zixun/50298)


  11. Xie, W.-B.; Li, Z.*; Asymmetric Synthesis of Ethers by Catalytic Alkene Hydro­alkoxy­lation, Synthesis 2020, 52, 2127-2146. (Invited review)


  12. Liu, D.-H., Marks, T. J.; Li, Z.*; Catalytic One-Pot Conversion of Renewable Platform Chemicals to Hydrocarbon and Ether Biofuels via Tandem Hf(OTf)4 + Pd/C Catalysis, ChemSusChem 2019, 12, 5217-5223. (Cover Feature: ChemSusChem 2019, 12, 5214.)



  13. Liu, H.; Zhu, Y.-L.; Li, Z.*; Catalytic amidation of natural and synthetic polyol esters with sulfonamides, Nat. Commun. 2019, 10, 3881. (自然科学基金委科学传播中心: http://www.nsfc.gov.cn/csc/20340/20343/45548/; 科学网: http://news.sciencenet.cn/sbhtmlnews/2019/10/350000.shtm)

      


  14. Xu, X.-L.; Li, Z.*; Catalytic Redox Chain Ring Opening of Lactones with Quinones To Synthesize Quinone-Containing Carboxylic Acids; Org. Lett., 2019, 21, 5078-5081. (CBG: https://www.chembeango.com/zixun/43665)


  15. Xu, X.-L.; Li, Z.*; Deciphering the Redox Chain Mechanism in the Catalytic Alkylation of Quinones; Synlett, 2018, 29, 1807-1813. (Invited Synpact article)


  16. Xu, X.-L.; Li, Z.* Catalytic Electrophilic Alkylation of p-Quinones through a Redox Chain Reaction; Angew. Chem. Int. Ed., 2017, 56, 8196–8200. (Top 3 Most Accessed Communications of June 2017; X-MOL: http://www.x-mol.com/news/8483)



PhD & Postdoc publications:

1.  Lohr, T. L.; Li, Z.; Marks, T. J.* Thermodynamic Strategies for C–O Bond Formation and Cleavage via Tandem Catalysis; Acc. Chem. Res.201649 (5), pp 824–834.

2.  Lohr, T. L.; Li, Z.; Assary, R. S.; Curtiss, L. A.; Marks, T. J.* Mono- and tri-ester hydrogenolysis using tandem catalysis. Scope and mechanism; Energy Environ. Sci.2016, 9 (2), pp 550–564. 

3.  Lohr, T. L.; Li, Z.; Marks, T. J.* Selective Ether/Ester C–O Cleavage of an Acetylated Lignin Model via Tandem Catalysis; ACS Catal.20155 (11), pp 7004–7007. 

4.  Lohr, T. L.†; Li, Z.†; Assary, R. S.; Curtiss, L. A.; Marks, T. J.* Thermodynamically Leveraged Tandem Catalysis for Ester RC(O)O–R′ Bond Hydrogenolysis. Scope and Mechanism; ACS Catal.,20155 (6), pp 3675–3679. (Equal contribution) 

5.  Li, Z.; Assary, R. S.; Atesin, A. C.; Curtiss, L. A.; Marks, T. J.* Rapid Ether and Alcohol C-O Bond Hydrogenolysis Catalyzed by Tandem High-valent Metal Triflate + Supported Pd Catalysts; J. Am. Chem. Soc., 2014136, 104-107. 

6.  Assary, R. S.*; Atesin, A. C.; Li, Z.; Curtiss, L. A.*; Marks, T. J.* Reaction Pathways and Energetics of Etheric C–O Bond Cleavage Catalyzed by Lanthanide Triflates; ACS Catal.20133, 1908–1914. 

7.  Olivares-Romero, J. L.; Li, Z.; Yamamoto, H.* Catalytic Enantioselective Epoxidation of Tertiary Allylic and Homoallylic alcohols; J. Am. Chem. Soc.2013135, 3411-3413. 

8.  Li, Z.; Yamamoto, H.* Hydroxamic Acids in Asymmetric Synthesis; Acc. Chem. Res.,2013,46, 506-518.

9.  Olivares-Romero, J. L.; Li, Z.; Yamamoto, H.*; Hf(IV)-Catalyzed Enantioselective Epoxidation of N-Alkenyl Sulfonamides and N-Tosyl Imines; J. Am. Chem. Soc.2012134, 5440-5443. (Top 20 Most Read Articles of March 2012

10.  Li, Z.; Yamamoto, H.*; Zirconium(IV)- and Hafnium(IV)-Catalyzed Highly Enantioselective Epoxidation of Homoallylic and Bishomoallylic Alcohols; J. Am. Chem. Soc. 2010132, 7878-7880. 

11.  Li, Z.; Zhang, W.; Yamamoto, H.*; Vanadium-Catalyzed Enantioselective Desymmetrization of meso-Secondary Allylic Alcohols and Homoallylic Alcohols; Angew. Chem. Int. Ed., 2008, 47, 7520-7522; Angew. Chem., 2008,120, 7630-7632.


本组成员

姚嘉麟

18级研究生    中央民族大学学士

邮箱:yaojl@@shanghaitech.edu.cn


罗雨季

19级研究生    中国药科大学学士 

邮箱:luoyj@@shanghaitech.edu.cn

叶雨萌

19级研究生    上海科技大学学士

邮箱:yeym@@shanghaitech.edu.cn


谷欢潮

21级研究生    上海科技大学学士

邮箱:guhch@@shanghaitech.edu.cn

张佳怡

21级研究生    南开大学学士

邮箱:zhangjy5@@shanghaitech.edu.cn

万远鼎

22级研究生    南昌大学学士

邮箱:wanyd2022@@shanghaitech.edu.cn

刘晨旭

22级研究生    大连理工大学学士

邮箱:liuchx2022@@shanghaitech.edu.cn

张诗倩

23级研究生    浙江工业大学学士

邮箱:zhangshq2023@@shanghaitech.edu.cn

欧阳坤辰

20级本科生

邮箱:ouyangkch@@shanghaitech.edu.cn

葛逸飞

20级本科生

邮箱:geyf@@shanghaitech.edu.cn

罗思弘

20级本科生

邮箱:luosh@@shanghaitech.edu.cn

姚羽泽

21级本科生

邮箱:yaoyz@@shanghaitech.edu.cn


过往成员在组学位/职位在组年份离组去向
刘华博士后2015-2019上海科技大学分析测试中心
Alain You Li博士后2022-2023Clariant
徐小龙博士2015-2020桑迪亚医药技术(上海)有限责任公司
刘东煌博士2015-2020南方科技大学化学系博士后
丁楠博士2016-2021宁波康龙化成公司
谢文斌博士2016-2021中国科学院大学本部
师展博士2018-2023南京三迭纪
张晓洁硕士2015-2017上海睿智化学
李舒婷硕士2019-2022University of Strasbourg
蒋佳晨硕士2020-2023毕得医药
刘宏研究生2015-2017上海科技大学
童敬庸研究生2017-2019
王彦昆研究生2020-2022
王娇娇本科生/科研助理2016-2019Michigan State University
祝亿灵本科生/科研助理2018-2019Boston College
唐一丰本科生2017-2019The University of Chicago
印思泳本科生2017-2019中国科学院上海有机化学研究所
Eric Yang暑期访问生2019The University of Chicago
康逸飞
本科生2019-2020
沈昊
本科生2019-2020
Baylor University
张子宁本科生2018-2021The University of Chicago
孙嘉寅本科生2018-2021京都大学
曹敦旭本科生2020-2022中国科学技术大学
赵怡临
本科生2021-2023中国科学院古脊椎动物与古人类研究所


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